Synthesis and High-Temperature Heat Capacity of LaMgAl11O19 and SmMgAl11O19 Hexaaluminates

The processes occurring during heating of a stoichiometric mixture of lanthanum, samarium, magnesium, and aluminum hydroxides synthesized by the reverse precipitation method have been studied by DTA/TG and X-ray powder diffraction methods. The conditions for the synthesis of single-phase LaMgAl 11 O...

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Published inRussian journal of inorganic chemistry Vol. 68; no. 11; pp. 1599 - 1605
Main Authors Gagarin, P. G., Guskov, A. V., Guskov, V. N., Khoroshilov, A. V., Ryumin, M. A., Gavrichev, K. S.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.11.2023
Springer Nature B.V
Subjects
Chemistry
Chemistry and Materials Science
Differential thermal analysis
High temperature
Hydroxides
Inorganic Chemistry
Lanthanum
Magnesium
Physical Methods of Investigation
Samarium
Specific heat
Synthesis
X ray powder diffraction
isobaric heat capacity
magnetoplumbite
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Summary:The processes occurring during heating of a stoichiometric mixture of lanthanum, samarium, magnesium, and aluminum hydroxides synthesized by the reverse precipitation method have been studied by DTA/TG and X-ray powder diffraction methods. The conditions for the synthesis of single-phase LaMgAl 11 O 19 and SmMgAl 11 O 19 samples of the magnetoplumbite structure type have been determined, and the isobaric heat capacity has been measured in the temperature range 317–1817 K, showing the absence of structural transformations in this range.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023623602064