Development of odorless thiols and sulfides and their applications to organic synthesis

Development of new odorless thiols (dodecanethiol, 4-n-heptylphenylmethanethiol, 4-trimethylsilylphenylmethanethiol, 4-trimethylsilylbenzenethiol) and an odorless sulfide (1-methylsulfanyldodecane) and their applications to dealkylation, Michael addition, Swern oxidation, and Corey-Kim oxidation are...

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Bibliographic Details
Published inMonatshefte für Chemie Vol. 135; no. 2; pp. 189 - 200
Main Authors Nishide, K, Ohsugi, S, Miyamoto, T, Kumar, K, Node, M
Format Journal Article
LanguageEnglish
Published WIEN Springer Nature 01.02.2004
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
Michael addition
ACTIVATED DIMETHYL-SULFOXIDE
ALPHA,BETA-UNSATURATED KETONES
SOFT NUCLEOPHILE SYSTEM
METHYL ETHERS
HARD ACID
CARBONYL-COMPOUNDS
alcohols
Corey-Kim oxidation
SECONDARY ALCOHOLS
COMBINATION SYSTEMS
ASYMMETRIC REDUCTION
dealkylation
Swern oxidation
PONNDORF-VERLEY REDUCTION
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Summary:Development of new odorless thiols (dodecanethiol, 4-n-heptylphenylmethanethiol, 4-trimethylsilylphenylmethanethiol, 4-trimethylsilylbenzenethiol) and an odorless sulfide (1-methylsulfanyldodecane) and their applications to dealkylation, Michael addition, Swern oxidation, and Corey-Kim oxidation are described.
ISSN:0026-9247
1434-4475
DOI:10.1007/s00706-003-0122-1