Synthesis of 2,7-Diazabicyclo[3.2.1]oct-3-ene Derivatives

Tetracyanoethylene adducts with ketones, 4-oxoalkane-1,1,2,2-tetracarbonitriles reacted with hydrogen chloride or phosphorus(III) chloride in 1,4-dioxane to give 3-chloro-6-oxo-2,7-diazabicyclo[3.2.1]oct-3-ene-4,5-dicarbonitrile derivatives.

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Bibliographic Details
Published inRussian journal of organic chemistry Vol. 55; no. 7; pp. 1009 - 1012
Main Authors Ershov, O. V., Lipin, K. V., Belikov, M. Yu, Ievlev, M. Yu
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.07.2019
Springer Nature
Springer Nature B.V
Subjects
Adducts
Chemistry
Chemistry and Materials Science
Chemistry, Organic
Derivatives
Hydrogen chloride
Ketones
Organic Chemistry
Physical Sciences
Science & Technology
bicyclic compounds
cyano group
2,7-diazabicyclo[3.2.1]oct-3-ene
4-oxoalkane-1,1,2,2-tetracarbonitriles
SALTS
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Summary:Tetracyanoethylene adducts with ketones, 4-oxoalkane-1,1,2,2-tetracarbonitriles reacted with hydrogen chloride or phosphorus(III) chloride in 1,4-dioxane to give 3-chloro-6-oxo-2,7-diazabicyclo[3.2.1]oct-3-ene-4,5-dicarbonitrile derivatives.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428019070170