Polyoxometalate/Lead Composite Anode for Efficient Oxygen Evolution in Zinc Electrowinning

• Published in: Journal of the Electrochemical Society Vol. 166; no. 4; pp. E129 - E136
• Main Author: Yang, Chang-jiang
• Format: Journal Article
• Language: English
• Published: The Electrochemical Society 2019
• ISSN: 0013-4651; 1945-7111
• DOI: 10.1149/2.0751904jes

Oxygen evolution in harsh high-acidic conditions has always been a challenge for both zinc electrowinning and hydrogen production. Lead and its alloys have met the requirements of zinc electrowinning up to now. This is the first time that a polyoxometalate/lead composite as an earth-abundant material has been investigated for use as anode in zinc electrowinning. A polyoxometalate/lead composite showed a high electrocatalytic activity and a long-term durability during an oxygen generation reaction in harsh high-acidic conditions of electrochemical accelerated corrosion tests. It could boost oxygen evolution by decreasing the Gibbs energy barriers of intermediates and showed a 10-fold higher electrochemically active surface area and one fifth of the polarization resistance compared to pure Pb. The overpotential of a Pb anode containing 1 wt % polyoxometalate was similar to that of a commercial Pb/0.75 wt % Ag anode, which implies the potential application of polyoxometalate/lead composite anodes in the hydrometallurgical industry.