Facile fabrication of urchin-like hollow boehmite and alumina microspheres with a hierarchical structure via Triton X-100 assisted hydrothermal synthesis

• Published in: CrystEngComm Vol. 17; no. 6; pp. 1318 - 1325
• Main Authors: Huang, Huihui, Wang, Lei, Cai, Yuan, Zhou, Caicheng, Yuan, Yuewei, Zhang, Xiaojun, Wan, Hui, Guan, Guofeng
• Format: Journal Article
• Language: English
• Published: 01.01.2015
• ISSN: 1466-8033; 1466-8033
• DOI: 10.1039/C4CE02133A

Hierarchically organized urchin-like hollow boehmite and alumina microspheres were successfully synthesized via a facile tert -octyl-phenyl polyoxyethylene ether (Triton X-100) assisted hydrothermal route using aluminum sulfate and urea as an aluminum source and a precipitant, respectively. The samples were characterized by X-ray diffraction (XRD), thermogravimetry (TG), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N 2 adsorption–desorption technique. SEM and TEM verified the hierarchically organized urchin-like hollow structure of the as-prepared samples with needles of about 1 μm length. The morphology and textual structure of boehmite and alumina can be handily controlled by adjusting the concentration of Triton X-100. Urchin-like alumina with a large S BET value of 146.91 m 2 g −1 , a pore volume of 0.92 cm 3 g −1 and a hierarchical structure was obtained at C TX = 0.01 M. Furthermore, a possible mechanism was also proposed for the formation of this hierarchically organized urchin-like boehmite.