The ESR Spectra of 2- and 6-Methoxyazulene Anion Radicals

The electron spin resonance spectra of 2- and 6-methoxyazulene anion radicals have been examined. The radicals were generated from neutral species either by electrolytic reduction in N,N-dimethylformamide or by the reduction with alkali metals in ethereal solvents. The experimental splitting constan...

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Bibliographic Details
Published inBulletin of the Chemical Society of Japan Vol. 44; no. 7; pp. 1905 - 1908
Main Authors Ikegami, Yusaku, Seto, Shuichi
Format Journal Article
LanguageEnglish
Published Tokyo The Chemical Society of Japan 01.07.1971
Chemical Society of Japan
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Summary:The electron spin resonance spectra of 2- and 6-methoxyazulene anion radicals have been examined. The radicals were generated from neutral species either by electrolytic reduction in N,N-dimethylformamide or by the reduction with alkali metals in ethereal solvents. The experimental splitting constants are explained satisfactorily in terms of the calculated spin densities by McLachlan’s procedure.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.44.1905