An emerging deep eutectic solvent based on halogen-bonds

A new deep eutectic solvent (DES) driven by halogen bonding (XB) was exploited. A family of eutectic mixtures in the liquid state was obtained by the combination of quaternary ammonium salts and dihalogens. The formation mechanism was discussed based on experiments and DFT calculations. It not only...

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Published inChemical communications (Cambridge, England) Vol. 58; no. 29; pp. 467 - 461
Main Authors Shi, Ruifen, Yu, Dongkun, Zhou, Fengyi, Yu, Jiangfeng, Mu, Tiancheng
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 07.04.2022
Subjects
Eutectics
Quaternary ammonium salts
Solvents
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Summary:A new deep eutectic solvent (DES) driven by halogen bonding (XB) was exploited. A family of eutectic mixtures in the liquid state was obtained by the combination of quaternary ammonium salts and dihalogens. The formation mechanism was discussed based on experiments and DFT calculations. It not only broadens the potential DES systems but unlocks the possibility of XB complexes as solvents. A new deep eutectic solvent (DES) driven by halogen bonding was exploited.
Bibliography:10.1039/d2cc00528j
Electronic supplementary information (ESI) available: Materials, synthesis, characterization, and diagrams. See DOI
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00528j