Diels-Alder reactions of masked o-benzoquinones with electron-rich dienophiles. Highly regio- and stereoselective synthesis of bicyclo [2.2.2]octenone derivatives

Highly regio- and stereoselective Diels-Alder reactions of masked o-benzoquinones with electron-rich dienophiles such as benzyl vinyl ether, dihydrofuran, phenyl vinyl sulfide and styrene that provide easy access to bicyclo[2.2.2]octenones are described.

Saved in:
Bibliographic Details
Published inSynlett no. 3; pp. 421 - 423
Main Authors Gao, SY, Lin, YL, Rao, PD, Liao, CC
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 2000
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
Diels-Alder reactions
CHEMISTRY
BICYCLO<2.2.2>OCTENONES
2-methoxyphenols
masked o-benzoquinones
electron-rich dienophiles
Online AccessGet more information

Cover

More Information
Summary:Highly regio- and stereoselective Diels-Alder reactions of masked o-benzoquinones with electron-rich dienophiles such as benzyl vinyl ether, dihydrofuran, phenyl vinyl sulfide and styrene that provide easy access to bicyclo[2.2.2]octenones are described.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2000-6537