Eu2+ doped calcium aluminate coatings by sol–gel methods

• Published in: Optical materials Vol. 27; no. 9; pp. 1537 - 1540
• Main Authors: Aitasalo, T., Hölsä, J., Jungner, H., Lastusaari, M., Niittykoski, J., Saarinen, J.
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Amsterdam Elsevier B.V 01.07.2005; Elsevier Science
• Subjects: Calcium aluminate; Coating; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Europium; Exact sciences and technology; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Other luminescence and radiative recombination; Other solid inorganic materials; Photoluminescence; Physics; Sol–gel; Thermoluminescence; Calcium aluminate; Coating; Sol–gel; Europium; Powders; Ternary compounds; Sol-gel; Luminescence; Doped materials; Europium additions; Spin-on coating; Dip coating; Sol-gel process; Paints; Thermoluminescence
• ISSN: 0925-3467; 1873-1252
• DOI: 10.1016/j.optmat.2005.03.001

Eu2+ doped calcium aluminate coatings were prepared by the dip- and spin-coating methods on α-alumina substrates. This kind of persistent luminescent coatings may replace the luminous paints used in many applications. If sol–gel methods are used the expense of preparing the coatings is relatively low. Annealing at 1050°C yielded the CaAl2O4:Eu2+ coatings with similar luminescence and thermoluminescence properties than those of the CaAl2O4:Eu2+ powders. At higher annealing temperatures, CaAl4O7 and CaAl12O19 were formed due to the diffusion of alumina from the substrate. The persistent luminescence was, however, relatively weak and thus more work is needed to optimize the multitude of parameters affecting the properties of the coatings.