General synthetic route to substituted bis(cyclopentadienyl)- and bis(indenyl)methanes

Several substituted bis(cyclopentadienyl)- and bis(indenyl)methanes were synthesized directly from the corresponding cyclopentadienes (indenes) and ketones in KOH/DME two-phase mixture.

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Bibliographic Details
Published inSynthesis (Stuttgart) no. 4; pp. 469 - 475
Main Authors Nifantev, IE, Ivchenko, PV, Kuzmina, LG, Luzikov, YN, Sitnikov, AA, Sizan, OE
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.04.1997
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
Michael addition
cyclopentadienes
indenes
DICHLORIDES
METALLOCENE CATALYSTS
ZIRCONOCENE
POLYMERIZATION
PROPYLENE
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Summary:Several substituted bis(cyclopentadienyl)- and bis(indenyl)methanes were synthesized directly from the corresponding cyclopentadienes (indenes) and ketones in KOH/DME two-phase mixture.
ISSN:0039-7881
DOI:10.1055/s-1997-1200