Copper-catalyzed N-arylation of amines with hypervalent iodonium salts

The copper-catalyzed N-arylation of amines with hypervalent iodonium compounds with secondary aliphatic amines, aromatic amines, azoles and amides was accomplished with catalytic CuI (10 mol%) or Cu(acac)(2) (5 mol%) in the presence of Na2CO3 or K2CO3 as a base in CH2Cl2 or toluene under mild condit...

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Bibliographic Details
Published inSynlett no. 7; pp. 1022 - 1024
Main Authors Kang, SK, Lee, SH, Lee, D
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 2000
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CUPRIC ACETATE
PHENYLATION
ACIDS
ARYL HALIDES
amination
ORGANOSTANNANES
hypervalent iodonium salts
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Summary:The copper-catalyzed N-arylation of amines with hypervalent iodonium compounds with secondary aliphatic amines, aromatic amines, azoles and amides was accomplished with catalytic CuI (10 mol%) or Cu(acac)(2) (5 mol%) in the presence of Na2CO3 or K2CO3 as a base in CH2Cl2 or toluene under mild conditions.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2000-6673