Synthesis of a magneto-chromatic tunable Fe3O4-HPAM colloid

• Published in: Materials chemistry and physics Vol. 310; p. 128470
• Main Authors: Aguilar, Nery M., Ledesma-Motolinía, M., San Román-Escudero, L., Silva-González, N.R., Toledo-Solano, M., Salazar-Kuri, U.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.12.2023
• Subjects: Fe3O4; Hydrolyzed polyacrylamide; Nanocomposite colloids; Photonic crystals; Fe3O4; Nanocomposite colloids; Hydrolyzed polyacrylamide; Photonic crystals
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2023.128470

Colloids of soft magnetic (Fe3O4) submicrometer particles, formed by magnetic nanoparticle clusters, coated with a polyelectrolyte (hydrolyzed polyacrylamide; HPAM) were fabricated successfully in situ with a highly controllable chemical approach. The formation mechanism of submicron particles was analyzed under the amounts of HPAM, urea, citrate, and metallic precursors. This mechanism was followed by SEM. The results showed that the physicochemical properties of the HPAM favored physical interactions with the reactants, promoting the formation of dense-packed magnetic micrometer clusters in one-step synthesis. The results showed that the physicochemical properties of the HPAM favored physical interactions with the reactants, promoting the formation of dense-packed magnetic micrometer clusters in one-step synthesis. The different estimated radii of these particles in solution (hydrodynamic and gyration) and dried (internal radius) decrease when the HPAM amount increases. Moreover, the particles exhibited a superparamagnetic behavior with a magnetization of 48.2 emu/g, 50.3 emu/g, and 54.3 emu/g when the amounts were 0.5 g, 1 g, and 2g of HPAM, respectively. Consequently, the optical response of the colloids to the application of a rotating magnetic field (RMF) parallel to the horizontal plane where they were located exhibited a behavior similar to photonic structures since their reflection spectrum showed a periodic diffraction color that closely matches the frequency of the RMF. •HPAM was used during the in-situ synthesis of magnetic nanoparticles to form colloids.•The Fe3O4-HPAM formation is based on the physical interactions between the reactants.•The magnetic saturation is not affected by the polymer concentration.•Applying a rotating magnetic field parallel to the plane induces an optical response.