Synthesis, Crystal Structure, and Properties of a Tetranuclear Copper(II) Complex With α-Naphthylacetic Acid

A tetranuclear copper(II) complex, Cu 4 (NAA) 8 (CH 3 CN) 2 (1) (HNAA = α-naphthylacetic acid), has been prepared and structurally characterized by IR, elemental analysis, TGA, and single-crystal X-ray diffraction. Complex 1 features a tetranuclear cluster based on two bridged binuclear units, which...

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Published inInorganic and nano-metal chemistry Vol. 44; no. 1; pp. 101 - 105
Main Authors Yin, Fu-Jun, Zhao, Hong, Xu, Xing-You, Yang, Xu-Jie
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis Group 02.01.2014
Taylor & Francis Ltd
Subjects
Antiferromagnetism
carboxylate
Copper
copper (II) complex
Crystal structure
magnetic property
Single crystals
Supramolecular frameworks
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Summary:A tetranuclear copper(II) complex, Cu 4 (NAA) 8 (CH 3 CN) 2 (1) (HNAA = α-naphthylacetic acid), has been prepared and structurally characterized by IR, elemental analysis, TGA, and single-crystal X-ray diffraction. Complex 1 features a tetranuclear cluster based on two bridged binuclear units, which is further interlinked into a higher dimensional supramolecular framework by intermolecular weak interactions. The weak antiferromagnetic behavior in 1 can be observed.
ISSN:1553-3174
2470-1556
1553-3182
2470-1564
DOI:10.1080/15533174.2013.768651