Nickel cobalt sulfide nanoneedle array as an effective alternative to Pt as a counter electrode in dye sensitized solar cells

Self supported nickel cobalt sulfide (NCS) nanoneedles are directly formed on FTO glass substrates by sulphurization of nickel cobalt oxide nanoneedles (grown by a hydrothermal method) in the presence of a hydrogen sulfide and argon gas mixture. These NCS nanoneedles when used as a counter electrode...

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Published inRSC advances Vol. 4; no. 16; pp. 8289 - 8294
Main Authors Banerjee, Abhik, Upadhyay, Kush Kumar, Bhatnagar, Sumit, Tathavadekar, Mukta, Bansode, Umesh, Agarkar, Shruti, Ogale, Satishchandra B.
Format Journal Article
LanguageEnglish
Published 2014
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Summary:Self supported nickel cobalt sulfide (NCS) nanoneedles are directly formed on FTO glass substrates by sulphurization of nickel cobalt oxide nanoneedles (grown by a hydrothermal method) in the presence of a hydrogen sulfide and argon gas mixture. These NCS nanoneedles when used as a counter electrode for dye sensitized solar cells (DSSCs) show efficient catalytic activity towards the I super(-)/I sub(3) super(-) redox couple, and lead to an impressive efficiency of 6.9%, compared with 7.7% obtained with a Pt electrode in similarly constructed devices.
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ISSN:2046-2069
2046-2069
DOI:10.1039/c3ra45981k