The development of a tannin-based after-treatment for cotton fabric dyed with sulphur dyes

• Published in: Pigment & resin technology Vol. 51; no. 2; pp. 227 - 235
• Main Authors: Mohtashim, Quratulain, Rigout, Muriel, Yousfani, Sheraz Hussain Siddique Hussain
• Format: Journal Article
• Language: English
• Published: Bradford Emerald Publishing Limited 07.02.2022; Emerald Group Publishing Limited
• Subjects: Biodegradability; Cellulose fibers; Cold; Cotton; Cotton fabrics; Dyeing; Dyes; Electron microscopes; Finishing; Hydrogen peroxide; Laboratories; Leuco dyes; Light fastness; Liquor; Oxidation; Reducing agents; Rubbing; Sodium; Sodium sulfide; Sulfides; Sulfur; Sulfur dyes; Tannins; Temperature; United Kingdom > UK; Sulphur dye; Wash fastness; Biodegradable; Tannin; After-treatment
• ISSN: 0369-9420; 1758-6941
• DOI: 10.1108/PRT-02-2021-0020

Purpose Sulphur dyes provide an inexpensive medium to dye cellulosic fibres with heavy shade depths. They offer moderate to good fastness to light and wet treatments. However, owing to the environmental hazard produced by the use of sodium sulphide, the practical implication of these dyes is steadily decreasing. Moreover, these dyes are prone to oxidation causing pronounced fading on exposure to laundering. This paper aims to present the green processing of sulphur dyes by using a biodegradable reducing agent in place of sodium sulphide to dye cotton fabrics. The study also proposes after-treatments with tannin to improve the fastness properties of the dyeings. Design/methodology/approach In this study, dyeings were produced on cotton fabric with a range of C.I. Leuco Sulphur dyes, which were reduced with sodium sulphide and glucose. Sulphur dyeings were after-treated with an environment-friendly tannin-based product (Bayprotect CL (BP)); subsequently, the after-treated samples were evaluated for colour strength, wash, light and rubbing fastness. Findings A novel after-treatment method was developed, which substantially improved the wash fastness of C.I. Leuco Sulphur Black 1 dyeing to ISO 105 C06/C09 washing. However, the degree of this improvement varied for the other sulphur dyes used. The surface morphology and the possible mechanisms for the improved fastness properties were also discussed. Research limitations/implications The effect of after-treatment was significant for improving the wash fastness of sulphur black dyeings in particular, while the effect on other colours was minor. Significant improvements were observed for light and wet rub fastness for most of the dyeings, which signifies the importance of tannins as a finishing agent. Practical implications It is observed that the tannin-based product, BP, is found to provide the photoprotective effect by improving the lightfastness of the dyeings. Future research may involve the exploration of various tannins as a finishing agent to sulphur dyeings. Originality/value This novel finishing technique is found significant for improving the wash fastness of sulphur black 1 dyeings for both the reducing systems. Improvements were also observed for light and wet rub fastnesses for most of the dyeings.