Two metal–organic frameworks with unique high-connected binodal network topologies: synthesis, structures, and catalytic properties

• Published in: CrystEngComm Vol. 14; no. 12; pp. 4210 - 4216
• Main Authors: Cui, Guang-Hua, He, Cui-Hong, Jiao, Cui-Huan, Geng, Jian-Chen, Blatov, Vladislav A.
• Format: Journal Article
• Language: English
• Published: 01.01.2012
• Subjects: Catalysis; Catalysts; Dyes; Ligands; Metal-organic frameworks; Networks; Synthesis; Three dimensional; Topology
• ISSN: 1466-8033; 1466-8033
• DOI: 10.1039/c2ce25264c

{[Cd sub(3)(btec)(btx) sub(0.5)( mu sub(3)-OH)(H sub(2)O)].H sub(2)O} sub(n) (1) and [Cu sub(2)(btec)(btx) sub(1.5)] sub(n) (2), two novel cadmium(ii) and copper(ii)-based high-connected metal-organic frameworks, with both 1,2,4,5-benzenetetracarboxylate (btec) and 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (btx) as mixed ligands were hydrothermally synthesized and structurally characterized. Both MOFs have three-dimensional (3D) structures, but different framework topologies and ligand linkage modes. 1 possesses an unprecedented binodal (4,12)-connected topology structure, in which the ligand btec serves as a rare dodecadentate and ordinary octadentate in two types of coordination modes. Meanwhile, 2 exhibits a binodal (4,7)-connected topological network with an enneadentate coordination geometry of the btec ligand. Both MOFs provide novel examples of designing and synthesizing novel binodal MOFs, and demonstrate that the 1,2,4,5-benzenetetracarboxylic acid ligand with rich coordination chemistry information is useful in the construction of binodal highly-connected nets. In addition, the catalytic performance of 2 has also been checked. 2 is active as a catalyst for the degradation of methyl orange.