Understanding Platinum Ionomer Interface Properties of Polymer Electrolyte Fuel Cells

• Published in: Journal of the Electrochemical Society Vol. 169; no. 6; pp. 64512 - 64520
• Main Authors: Qi, Yongzhen, Morimoto, Yu, Shibata, Masao Suzuki, Gao, Ziliang, Sabarirajan, Dinesh C., Haug, Andrew T., Zenyuk, Iryna V.
• Format: Journal Article
• Language: English
• Published: United States IOP Publishing 01.06.2022; The Electrochemical Society
• ISSN: 0013-4651; 1945-7111
• DOI: 10.1149/1945-7111/ac774f

A well-designed cathode catalyst layer with optimal ionomer distribution is critical to minimizing amount of Platinum (Pt) content in polymer electrolyte fuel cells (PEFCs). The impact of Pt loading, ionomer content and carbon support types on the catalyst/ionomer interface were also investigated at dry and wet conditions. Higher Pt loadings resulted in higher double layer capacity (C dl ) and similar electrochemical surface area (ECSA) due to well dispersed ionic phase material. Higher ionomer content resulted in higher ionic conductivity but also showed similar SO 3 − group coverage. High surface area (HSA) carbon support had larger ECSA and C dl at both dry and wet conditions, as less agglomerated Pt was well dispersed in the meso-pores of the support. Lower SO 3 − group coverages were observed for HSA carbon than for Vulcan carbon due to Pt particles being buried within the porous HSA carbon support. The effect of cell conditioning and voltage recovery on the PEFC cathode catalyst layer was shown to have minimal impact on SO 3 − group coverage despite a decrease in C dl and ECSA due to the size increase of Pt particles. At dry condition, a significant increases in SO 3 − group coverage were observed for all MEAs due to higher adsorptivity of ionomer in dry conditions.