Rheological characteristics PBAT/organoclay compounds

• Published in: REM - International Engineering Journal Vol. 72; no. 2; pp. 243 - 250
• Main Authors: Santos, Tiago Tibério dos, Almeida, Tatiara Gomes, Pereira, Camila Ariana Becker, Agrawal, Pankaj, Canedo, Eduardo Luis, Carvalho, Laura Hecker de
• Format: Journal Article
• Language: English
• Published: Fundação Gorceix 01.06.2019
• Subjects: ENGINEERING, MECHANICAL; GEOLOGY; MECHANICS; METALLURGY & METALLURGICAL ENGINEERING; nanocomposites; organoclay; PBAT; rheometry; PBAT; rheometry; organoclay; nanocomposites
• ISSN: 2448-167X; 2448-167X
• DOI: 10.1590/0370-44672018720077

Abstract The rheological behavior of poly (butylene adipate-co-terephthalate) (PBAT) and its composites prepared with three different organoclays was investigated. Composites containing up to 7.5%, w/w organoclay, were prepared by two routes: (a) direct melt blending in an internal laboratory mixer with high intensity rotors and (b) concentrates (prepared in the internal mixer) with 50 %, by weight, of the organoclays diluted in a co-rotating twin screw extruder equipped with a high intensity mixing thread operating at a nominal speed of 480 rpm. The samples were characterized by both torque and parallel plate rheometry. Results indicate that nanodispersions in the clay layers were obtained during processing and that, like the pure matrix, at high shear rates, the organoclay compounds follow the power law, although with higher viscosity. It is believed that the interaction of the polymer with the organoclay is responsible for the increase in melt viscosity (observed by increases in torque and relaxation time) of the hybrid systems.