5,5′-Thiobis(4-chloro-3H-1,2-dithiole-3-thione)

3H-1,2-Dithiole-3-thiones are important compounds with many types of significant pharmacological activity. Although many derivatives of this class have been described in the literature, their thioethers have not previously been obtained. In this communication, it is shown that the reaction of 4,5-di...

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Bibliographic Details
Published inMolBank Vol. 2022; no. 2; p. M1371
Main Authors Ogurtsov, Vladimir A., Rakitin, Oleg A.
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 27.05.2022
Subjects
3H-1,2-dithiole-3-thiones
5,5′-thiobis(4-chloro-3H-1,2-dithiole-3-thione)
Chemical analysis
Chemical synthesis
Composition
Conflicts of interest
Heterocyclic compounds
Hydrocarbons
Infrared spectroscopy
Isocyanates
Mass spectrometry
Methods
NMR
Nuclear magnetic resonance
nucleophilic substitution
Potassium
potassium isocyanate
Properties
Scientific imaging
Russia
United States > US
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Summary:3H-1,2-Dithiole-3-thiones are important compounds with many types of significant pharmacological activity. Although many derivatives of this class have been described in the literature, their thioethers have not previously been obtained. In this communication, it is shown that the reaction of 4,5-dichloro-3H-1,2-dithiole-3-thione with potassium isocyanate unexpectedly gave 5,5′-thiobis(4-chloro-3H-1,2-dithiole-3-thione). The structure of the synthesized compound was established by elemental analysis, high-resolution mass spectrometry, 13C NMR and IR spectroscopy, and mass spectrometry.
ISSN:1422-8599
1422-8599
DOI:10.3390/M1371