1,4-Bis(triphenylphosphonium)-2-butene Peroxodisulfate: An Efficient Reagent for Synthesis of β-Nitrato Alcohols

A simple and efficient method for the ring opening of epoxides to β -hydroxy nitrates has been achieved in the presence of ammonium nitrate and 1,4-bis(triphenylphosphonium)-2-butene peroxodisulfate.

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Bibliographic Details
Published inSynthetic communications Vol. 39; no. 23; pp. 4239 - 4248
Main Authors Badri, Rashid, Gorjizadeh, Maryam
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 05.11.2009
Subjects
1,4-Bis(triphenylphosphonium)-2-butene peroxodisulfate
epoxide
hydroxy nitrate
regioselectivity
ring opening
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Summary:A simple and efficient method for the ring opening of epoxides to β -hydroxy nitrates has been achieved in the presence of ammonium nitrate and 1,4-bis(triphenylphosphonium)-2-butene peroxodisulfate.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397910902898593