New L-Serine Derivative Ligands as Cocatalysts for Diels-Alder Reaction
New L-serine derivative ligands were prepared and tested as cocatalyst in the Diels-Alder reactions between cyclopentadiene (CPD) and methyl acrylate, in the presence of several Lewis acids. The catalytic potential of the in situ formed complexes was evaluated based on the reaction yield. Bidentate...
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Published in | ISRN Organic Chemistry Vol. 2013; pp. 217675 - 5 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Egypt
Hindawi Publishing Corporation
05.12.2013
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Online Access | Get full text |
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Summary: | New L-serine derivative ligands were prepared and tested as cocatalyst in the Diels-Alder reactions between cyclopentadiene (CPD) and methyl acrylate, in the presence of several Lewis acids. The catalytic potential of the in situ formed complexes was evaluated based on the reaction yield. Bidentate serine ligands showed good ability to coordinate medium strength Lewis acids, thus boosting their catalytic activity. The synthesis of the L-serine ligands proved to be highly efficient and straightforward. |
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Bibliography: | Academic Editors: P. S. Andrada, M. W. Paixao, and N. Zanatta |
ISSN: | 2090-5149 2090-5157 2090-5157 |
DOI: | 10.1155/2013/217675 |