Bimetallic AuCu nanoclusters-based florescent chemosensor for sensitive detection of Fe3+ in environmental and biological systems

• Published in: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 209; pp. 202 - 208
• Main Authors: Shojaeifard, Zahra, Heidari, Nahid, Hemmateenejad, Bahram
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.02.2019
• Subjects: AuCu nanoclusters; Bimetallic nanoclusters; Ferric ions; Fluorescence; Sensor; Fluorescence; Bimetallic nanoclusters; AuCu nanoclusters; Ferric ions; Sensor
• ISSN: 1386-1425
• DOI: 10.1016/j.saa.2018.10.042

Assays of ferric ion (Fe3+) with high sensitivity and selectivity have been required to evaluate its amount in environmental and biological systems. Herein, a novel fluorometric penicillamine-capped bimetallic gold-copper nanoclusters (PA-AuCu bi-MNCs) sensor was constructed for facile, environmentally friendly and quantitative detection of Fe3+ through inner filter effect (IFE) mechanism. One-step green synthetic approach was applied for the synthesis of AuCu bi-MNCs by using d-penicillamine (D-PA) as template and stabilizer. In the presence of Fe3+, the emission of the PA-AuCu bi-MNCs was hindered that caused selective quenching of the fluorescence intensity. The response to Fe3+ allows for two linear dynamic ranges of 5.0 × 10−7 M–7.0 × 10−6 M and 7.0 × 10−6 M–1.0 × 10−4 M with a detection limit of 0.1 μM, which is approximately 53 times lower than the maximum level (5.37 μM) of Fe3+ in drinking water that had been reported by the World Health Organization. The independency of the system from most of the interferences is the important feature of this work. Beside the appropriate selectivity of the proposed method, it shows a considerable operation in various environmental samples including rain water, three types of river water and also in human blood serum as a biological matrix. [Display omitted] •A fluorometric penicillamine-capped bimetallic gold-copper nanocluster sensor was constructed for Fe3+.•In the presence of Fe3+, the emission of the PA-AuCu bi-MNCs was hindered.•The mechanism of selective quenching is thought to be inner filter effect.•The response to Fe3+ allows for two linear dynamic ranges of 5.0 × 10−7 M–7.0 × 10−6 M and 7.0 × 10−6 M–1.0 × 10−4 M.