Application of electrochemical impedance spectroscopy to the study of surface processes

The application of Electrochemical Impedance Spectroscopy to the study of surface electrode processes is reviewed. The impedance expressions and the physical meaning of the parameters included in them are shown for three surface processes: adsorption kinetics, diffusion towards partially blocked ele...

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Bibliographic Details
Published inCollection of Czechoslovak chemical communications Vol. 76; no. 12; pp. 1825 - 1854
Main Authors Rueda Rueda, Manuela, Prieto Dapena, Francisco
Format Journal Article
LanguageEnglish
Published Prague Blackwell Publishing Ltd 01.01.2011
Subjects
Behavior
Chemistry
Kinetics
Mercury
Spectrum analysis
Studies
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Summary:The application of Electrochemical Impedance Spectroscopy to the study of surface electrode processes is reviewed. The impedance expressions and the physical meaning of the parameters included in them are shown for three surface processes: adsorption kinetics, diffusion towards partially blocked electrodes and surface confined redox reactions. The models are applied to selected examples, showing the capability of Electrochemical Impedance Spectroscopy to obtain fundamental kinetic information of these processes. A review with 83 references.
ISSN:1212-6950
1212-6950
2192-6506
DOI:10.1135/cccc2011118