Effective Upgrading of Levulinic Acid into Hexyl Levulinate Using AlCl3·6H2O as a Catalyst

• Published in: Biomass (Basel, Switzerland) Vol. 3; no. 3; pp. 266 - 278
• Main Authors: D’Ambrosio, Valeria, Pastore, Carlo
• Format: Journal Article
• Language: English
• Published: MDPI AG 01.08.2023
• Subjects: AlCl3·6H2O; catalyst recoverability; direct esterification; hexyl levulinate; process intensification
• ISSN: 2673-8783; 2673-8783
• DOI: 10.3390/biomass3030016

AlCl3·6H2O was used as a catalyst in the esterification reaction of levulinic acid with 1-hexanol for producing hexyl levulinate, a compound that finds applications in several industrial sectors and represents an excellent candidate to be used in diesel fuel blends. A kinetic and thermodynamic study of the esterification reaction was performed, considering four different temperatures (338, 348, 358, and 368 K), an acid: alcohol: catalyst 1:1:0.01 molar ratio, and a reaction time of 72 h. An optimization study was then carried out, evaluating the effect of alcohol and catalyst amounts, and, in the best reaction conditions (acid:alcohol:catalyst 1:2:0.1), a very high levulinic acid conversion (92.5%) was achieved. By using AlCl3·6H2O, alongside the high reaction yield, the product purification was also simplified, being such a catalyst able to trap most of the water in a different phase than hexyl levulinate, and, furthermore, it was found to be completely recoverable and reusable for several reaction cycles, without losing its catalytic effectiveness. The use of AlCl3·6H2O, therefore, represents a promising effective green route for obtaining hexyl levulinate.