Synthesis of bimetallic Co–Pt/cellulose nanocomposites for catalytic reduction of p -nitrophenol

• Published in: Reaction chemistry & engineering Vol. 7; no. 3; pp. 641 - 652
• Main Authors: Landge, Vividha K., Hakke, Vikas S., Kakunuri, Manohar, Babu, G. Uday B., Boczkaj, Grzegorz, Sonawane, Shirish H.
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 01.03.2022
• Subjects: Aminophenol; Bimetals; Catalysts; Catalytic activity; Cellulose acetate; Cellulose fibers; Chemical reduction; Chemical synthesis; Cobalt; Emission analysis; Energy dispersive X ray analysis; Field emission microscopy; Field emission spectroscopy; Fourier transforms; Infrared spectroscopy; Nanocomposites; Nanofibers; Nanoparticles; Nitrophenol; Parameters; Platinum; Scanning electron microscopy; Spectrum analysis; Wastewater treatment; X ray analysis
• ISSN: 2058-9883; 2058-9883
• DOI: 10.1039/D1RE00422K

In this study, bimetallic nanoparticles (NPs) of Co–Pt anchored on cellulose nanofibers (CNFs) for catalytic applications were synthesized via a sonochemical approach. The electro-spinning technique was employed for the synthesis of CNFs from cellulose acetate. The thorough characterization of synthesised Co–Pt/CNF nanocomposites was performed with the help of scanning electron microscopy (SEM), Fourier transform infra-red (FT-IR) spectroscopy, field emission scanning electron microscopy (FESEM) with energy dispersive X-ray analysis (EDX), and X-ray diffraction (XRD). This method leads to the facile preparation of Co–Pt bimetallic NPs using cellulose as a support. The synthesized nanocomposites were used for the p -nitrophenol ( p -NP) reduction to p -aminophenol ( p -AP) with excess sodium borohydride (NaBH 4 ) to assess their catalytic performance. The effects of various parameters on the performance of the catalyst were also investigated. The investigated parameters are catalyst loading, initial p -NP concentration and NaBH 4 concentration. The extent of p -NP reduction into p -AP over Co–Pt/CNF nanocomposites with an excess of NaBH 4 was examined with UV-vis spectroscopy. The p -NP reduction to p -AP over Co–Pt NPs anchored on CNFs was achieved within 98 seconds with around 100% conversion. The efficiency of the catalyst did not vary significantly up to 5 consecutive cycles. The excellent catalytic activity ( K app = 0.028 s −1 ) and stability of the as-synthesized Co–Pt nanoparticles supported on CNFs make them potential catalysts for nitrophenol reduction and wastewater treatment.