Silver-decorated hierarchical cuprous oxide micro/nanospheres as highly effective surface-enhanced Raman scattering substrates

A facile and simple route to manufacture active surface-enhanced Raman scattering (SERS) substrate based on Ag-decorated Cu2O micro/nanospheres on Cu foil was systematically investigated. Hierarchical Cu2O micro/nanostructure transfers from CuO nanosheets and Cu(OH)2 nanowires by means of thermally...

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Published inOptics express Vol. 22; no. 12; pp. 14617 - 14624
Main Authors Fu, Shih-Yu, Hsu, Yu-Kuei, Chen, Mei-Hsin, Chuang, Chin-Jung, Chen, Ying-Chu, Lin, Yan-Gu
Format Journal Article
LanguageEnglish
Published United States 16.06.2014
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Summary:A facile and simple route to manufacture active surface-enhanced Raman scattering (SERS) substrate based on Ag-decorated Cu2O micro/nanospheres on Cu foil was systematically investigated. Hierarchical Cu2O micro/nanostructure transfers from CuO nanosheets and Cu(OH)2 nanowires by means of thermally reducing the oxides from Cu2+ to Cu1+ at temperature of 500 °Cunder nitrogen atmosphere. The subsequent decoration of Ag on Cu2O nanostructural substrate was carried out by means of thermal evaporator deposition. Using 4-aminothiophenol (4-ATP) as probing molecules, the SERS experiments showed that the Ag-decorated Cu2O micro/nanospheres exhibit excellent detecting performance, which could be used as effective SERS substrate for ultrasensitive detection. Additionally, these novel hierarchical SERS substrates showed good reproducibility and a linear dependence between analyte concentrations and intensities, revealing the advantage of this method for easily scale-up production.
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ISSN:1094-4087
1094-4087
DOI:10.1364/OE.22.014617