Synthesis of novel tetrathiafulvalene derivatives with thiacrowns

Condensation of dicaesium 2-thioxo-1,3-dithiole-4,5-diselenolate (DSIT) with bis-alkylating polythioethers in high dilution leads to the thiacrown compounds 4-7, On treatment with triethyl phosphite, compounds 5-7 are converted into tetrathiafulvalene derivatives 8-10, The crystal structure of 6, an...

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Published inJournal of the Chemical Society, Perkin Transactions 1 no. 16; pp. 1995 - 1998
Main Authors Wagner, M, Madsen, D, Markussen, J, Larsen, S, Schaumburg, K, Lubert, KH, Becher, J, Olk, RM
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.08.1996
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CHEMISTRY
CROWN
DESIGN
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Summary:Condensation of dicaesium 2-thioxo-1,3-dithiole-4,5-diselenolate (DSIT) with bis-alkylating polythioethers in high dilution leads to the thiacrown compounds 4-7, On treatment with triethyl phosphite, compounds 5-7 are converted into tetrathiafulvalene derivatives 8-10, The crystal structure of 6, and cyclic voltammograms of the tetrathiafulvalenes 9 and 10, are discussed.
ISSN:0300-922X
1364-5463
DOI:10.1039/p19960001995