Halogen bonding two-point recognition with terphenyl derivatives

Two-point recognition involving neutral terphenyl-based halogen bond donors (halogen-based Lewis acids) was investigated. Oxadiazole and pyridazole derivatives were identified by DFT as suitable binding partners, even though gas-phase binding was weak. X-ray studies provided convincing evidence of t...

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Published inNew journal of chemistry Vol. 42; no. 13; pp. 10476 - 10480
Main Authors Stoesser, J., Rojas, G., Bulfield, D., Hidalgo, P. I., Pasán, J., Ruiz-Pérez, C., Jiménez, C. A., Huber, S. M.
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2018
Subjects
Binding
Derivatives
Recognition
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Summary:Two-point recognition involving neutral terphenyl-based halogen bond donors (halogen-based Lewis acids) was investigated. Oxadiazole and pyridazole derivatives were identified by DFT as suitable binding partners, even though gas-phase binding was weak. X-ray studies provided convincing evidence of two-point binding in the solid state, while solution data hinted at weak association.
ISSN:1144-0546
1369-9261
DOI:10.1039/C8NJ00962G