Mercury(II) Trichloroacetate. Part II. Formation and Use as a Versatile Reagent in Ferrocene Chemistry

The preparation of a methanolic solution of mercury(II) trichloroacetate is described. This reagent is used in an improved decamercuration of ferrocene. Decamercurated ferrocene is converted to decahaloferrocenes and used as the starting material in a new method for the synthesis of decadeuteroferro...

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Published inSynthesis and reactivity in inorganic and metal-organic chemistry Vol. 27; no. 10; pp. 1543 - 1551
Main Authors Neto, Alberto Federman, Borges, Aurea Donizete Lanchote, de Arruda Campos, Ivan Pérsio, Miller, Joseph
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 01.11.1997
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Summary:The preparation of a methanolic solution of mercury(II) trichloroacetate is described. This reagent is used in an improved decamercuration of ferrocene. Decamercurated ferrocene is converted to decahaloferrocenes and used as the starting material in a new method for the synthesis of decadeuteroferrocene. Referee I: T. J. Haas Referee II: P. F. Brandt
ISSN:0094-5714
1532-2440
DOI:10.1080/00945719708003158