Synthesis and transition-metal complexes of new cross-bridged tetraamine ligands

New cross-bridged tetraamine ligands (bicyclo[6.6.2], [6.5.2] and [5.5.2] systems) are synthesized; complexation of Cu-II and Ni-II demonstrates that the ligands coordinate selected metals in a cleft.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 8; pp. 947 - 948
Main Authors Weisman, GR, Wong, EH, Hill, DC, Rogers, ME, Reed, DP, Calabrese, JC
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 1996
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
TRIDENTATE
MACROCYCLIC LIGANDS
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Summary:New cross-bridged tetraamine ligands (bicyclo[6.6.2], [6.5.2] and [5.5.2] systems) are synthesized; complexation of Cu-II and Ni-II demonstrates that the ligands coordinate selected metals in a cleft.
ISSN:1359-7345
1364-548X
DOI:10.1039/cc9960000947