Facile fabrication of highly efficient bifunctional polydopamine–polyethyleneimine copolymerization‐modified magnetic material and its effective applications for both adsorption of gold ions and catalytic reduction of 4‐nitrophenol

• Published in: Journal of applied polymer science Vol. 141; no. 10
• Main Authors: Wu, Xiaoqiong, Zhang, Wansong, Yin, Ping, Xu, Qiang, Yang, Zhenglong, Xu, Yanbin, Liu, Xiguang, Wang, Feng, Wang, Ying, Cai, Honglan
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 10.03.2024; Wiley Subscription Services, Inc
• Subjects: Adsorption; Ambient temperature; Aminophenol; bifunctional polymer magnetic material; Catalysis; catalytic reduction of 4‐nitrophenol; Chemical reduction; Composite materials; Copolymerization; copolymerization modification; Gluons; Gold; gold ion adsorption; Heavy metals; Industrial wastes; Iron oxides; Magnetic materials; Nitrophenol; polydopamine; Polyethyleneimine; Polymer matrix composites; Polymers; Reaction mechanisms; Wastewater
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.55043

The heavy metal ions and organic pollutants are major harmful substances in wastewater because of their toxicity on human health and environment. Nowadays, the adsorption–catalysis treatment to remove them simultaneously is still a challenge because of their different reaction mechanisms. Herein, a novel bifunctional polymer magnetic material Fe3O4@PDA‐PEI was successfully developed through a facile co‐deposition method by the copolymerization modification of polydopamine (PDA) and polyethyleneimine (PEI) on magnetic ferroferric oxide, which can both be utilized for both heavy metal ion removal from simulated industrial wastewater and further effective catalytic reduction of toxic 4‐nitrophenol (4‐NP) to useful 4‐aminophenol. The maximum adsorption capacity of Fe3O4@PDA‐PEI for gold ions was 465.12 mg/g at 35°C, and the adsorption thermodynamic parameters ΔG, ΔH, and ΔS of Fe3O4@PDA‐PEI (m(PDA):m(PEI) = 2:1) were −5.28 (35°C), 25.58, and 111.30 J K−1 mol−1, respectively. In addition, a sustainable strategy of converting gold ions to gold nanoparticles has been demonstrated for additional catalytic functionality of Fe3O4@PDA‐PEI, and Fe3O4@PDA‐PEI‐Au could effectively catalyze the reduction of 4‐NP at ambient temperature within 9 min. Fe3O4@PDA‐PEI with the advantages of facile fabrication, easy separation, excellent adsorption, and catalysis performance could be used as a promising polymer composite material in complicated wastewater environment. © 2023 Wiley Periodicals LLC. The preparation process of the bifunctional polymer magnetic material Fe3O4@PDA‐PEI and its adsorption for gold ions, and the further catalytic reduction performance for 4‐NP.