Nanocrystalline magnetic materials obtained by flash annealing

• Published in: Materials research (São Carlos, São Paulo, Brazil) Vol. 2; no. 2; pp. 67 - 73
• Main Authors: Murakami, R.K., Villas-Boas, V.
• Format: Journal Article
• Language: English; Portuguese
• Published: ABM, ABC, ABPol 01.04.1999; Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)
• Subjects: ENGINEERING, CHEMICAL; flash annealing permanent magnets; MATERIALS SCIENCE, MULTIDISCIPLINARY; METALLURGY & METALLURGICAL ENGINEERING; nanocrystalline magnetic materials; nanocrystalline magnetic materials; flash annealing permanent magnets
• ISSN: 1516-1439; 1980-5373; 1516-1439
• DOI: 10.1590/S1516-14391999000200005

The aim of the present work was to produce enhanced-remanence nanocrystalline magnetic material by crystallizing amorphous or partially amorphous Pr4.5Fe77B18.5 alloys by the flash annealing process, also known as the dc-Joule heating process, and to determine the optimal conditions for obtaining good magnetic coupling between the magnetic phases present in this material. Ribbons of Pr4.5Fe77B18.5 were produced by melt spinning and then annealed for 10-30 s at temperatures 500 - 640 °C by passing current through the sample to develop the enhanced-remanence nanocrystalline magnetic material. These materials were studied by X-ray diffraction, differential thermal analysis and magnetic measurements. Coercivity increases of up to 15% were systematically observed in relation to furnace-annealed material. Two different samples were carefully examined: (i) a sample annealed at 600 °C which showed the highest coercive field Hc and remanence ratio Mr/Ms and (ii) a sample annealed at 520 °C which showed phase separation in the second quadrant demagnetization curve. Our results are in agreement with other studies which show that flash annealing improves the magnetic properties of some amorphous ferromagnetic ribbons.