Frontispiece: Fine Substituent Effects in Sandwich Complexes: A Threshold Ionization Study of Monosubstituted Chromium Bisarene Compounds

Substituent Effects Transition metal bisarene compounds, like metallocenes, form one of the most interesting and intriguing families of organometallics. Mass‐analyzed threshold ionization (MATI) spectra of jet‐cooled [(PhH)(PhR)Cr] complexes (R=Me, Ph) reveal with unprecedented accuracy the effects...

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Published inChemistry : a European journal Vol. 22; no. 14; pp. np - n/a
Main Authors Ketkov, Sergey Yu, Markin, Gennady V., Tzeng, Sheng Y., Tzeng, Wen B.
Format Journal Article
LanguageEnglish
Published Weinheim Blackwell Publishing Ltd 24.03.2016
Wiley Subscription Services, Inc
Subjects
Benzene
Chemistry
Chromium
Chromium compounds
density-functional calculations
Electronic structure
Ionization
Metallocenes
Metalorganic compounds
Metals
Organometallic compounds
Phenyls
sandwich complexes
Spectra
substituent effects
Thresholds
Transition metals
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Summary:Substituent Effects Transition metal bisarene compounds, like metallocenes, form one of the most interesting and intriguing families of organometallics. Mass‐analyzed threshold ionization (MATI) spectra of jet‐cooled [(PhH)(PhR)Cr] complexes (R=Me, Ph) reveal with unprecedented accuracy the effects of methyl and phenyl groups on the electronic structure of bis(benzene)chromium. These “pure” substituent effects provide new insights into the changes in electronic structure caused by the mutual substituent influence in bisarene complexes. For more details, see the Communication by S. Ketkov et al. on page 4690 ff.
Bibliography:istex:CD94159BA265B025AE212A1C6CCEFBC4BE058119
ark:/67375/WNG-P70XF62K-V
ArticleID:CHEM201681461
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201681461