Electrical properties of boundary layers of fatty acids

Nonlinear current-voltage and coulomb-voltage characteristics with a hysteresis loop, which is peculiar to ferroelectrics, were observed in the boundary layers of individual saturated organic acids and oleic acid which have a domain structure and also an anomalously high conductivity which correspon...

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Bibliographic Details
Published inProgress in surface science Vol. 40; no. 1-4; pp. 341 - 346
Main Authors Deryagin, B.V., Snitkovskii, M.M.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.05.1992
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Summary:Nonlinear current-voltage and coulomb-voltage characteristics with a hysteresis loop, which is peculiar to ferroelectrics, were observed in the boundary layers of individual saturated organic acids and oleic acid which have a domain structure and also an anomalously high conductivity which corresponds, in its order of magnitude, to the lower conductivity limit for metals. These effects are related with the formation of a volume space charge and by the cording of the current (formation of conductivity channels). The electrical properties of the boundary layers change in relation to the thickness: for subcritical thicknesses Ohm's Law is obeyed but for larger thicknesses strong field effects are observed. The thickness at which the system changes into the nonconducting stage has meaning as a physical characteristic of the system.
ISSN:0079-6816
1878-4240
DOI:10.1016/0079-6816(92)90061-L