Optical properties of red-emitting Ba1.982ZnS3:0.018Eu phosphor
•We synthesized the red-emitting Ba1.982ZnS3:0.018Eu phosphor.•The zero phonon line energy, Stokes shift, and red shift were measured.•The feasibility of the phosphor-converted LED was examined. Ba2(1−x)ZnS3:2xEu (x = 0.001, 0.003, 0.005, 0.007, 0.009, and 0.011) were synthesized via a solid-state r...
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| Published in | Materials letters Vol. 347; p. 134603 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
15.09.2023
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| Abstract | •We synthesized the red-emitting Ba1.982ZnS3:0.018Eu phosphor.•The zero phonon line energy, Stokes shift, and red shift were measured.•The feasibility of the phosphor-converted LED was examined.
Ba2(1−x)ZnS3:2xEu (x = 0.001, 0.003, 0.005, 0.007, 0.009, and 0.011) were synthesized via a solid-state reaction. An assessment of the optimal reaction temperature and composition of the activator Eu2+ ion (x) revealed that the brightest emission was obtained from the Ba1.982ZnS3:0.018Eu prepared at 900 °C. Because Ba1.982ZnS3:0.018Eu exhibits broad absorption and emission bands at ∼475 and ∼650 nm, respectively, it is a good candidate for red-emitting phosphors excited by blue light-emitting diodes. Furthermore, zero-phonon line energy, Stokes shift, and redshift were also calculated. |
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| AbstractList | •We synthesized the red-emitting Ba1.982ZnS3:0.018Eu phosphor.•The zero phonon line energy, Stokes shift, and red shift were measured.•The feasibility of the phosphor-converted LED was examined.
Ba2(1−x)ZnS3:2xEu (x = 0.001, 0.003, 0.005, 0.007, 0.009, and 0.011) were synthesized via a solid-state reaction. An assessment of the optimal reaction temperature and composition of the activator Eu2+ ion (x) revealed that the brightest emission was obtained from the Ba1.982ZnS3:0.018Eu prepared at 900 °C. Because Ba1.982ZnS3:0.018Eu exhibits broad absorption and emission bands at ∼475 and ∼650 nm, respectively, it is a good candidate for red-emitting phosphors excited by blue light-emitting diodes. Furthermore, zero-phonon line energy, Stokes shift, and redshift were also calculated. |
| ArticleNumber | 134603 |
| Author | Huh, Young-Duk Cho, Young-Sik Kim, Eung-Dab |
| Author_xml | – sequence: 1 givenname: Young-Sik surname: Cho fullname: Cho, Young-Sik – sequence: 2 givenname: Eung-Dab surname: Kim fullname: Kim, Eung-Dab – sequence: 3 givenname: Young-Duk orcidid: 0000-0003-4111-4509 surname: Huh fullname: Huh, Young-Duk email: ydhuh@dankook.ac.kr |
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| Snippet | •We synthesized the red-emitting Ba1.982ZnS3:0.018Eu phosphor.•The zero phonon line energy, Stokes shift, and red shift were measured.•The feasibility of the... |
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| SubjectTerms | Ba2ZnS3:Eu Phosphor-converted LED Red-emitting phosphor Spectroscopic parameters |
| Title | Optical properties of red-emitting Ba1.982ZnS3:0.018Eu phosphor |
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