Spatially resolved EDS, XRF and LIBS measurements of the chemical composition of duplex stainless steel welds: A comparison of methods

• Published in: Spectrochimica acta. Part B: Atomic spectroscopy Vol. 193; p. 106439
• Main Authors: Quackatz, Lukas, Griesche, Axel, Kannengiesser, Thomas
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier B.V 01.07.2022; Elsevier BV
• Subjects: Ablation; Alloying elements; Analytical methods; Austenitic stainless steels; Chemical composition; Chemical elements; Chemical industry; Cold surfaces; Corrosion; Duplex stainless steels; EDS; Element vaporization; Elements; Energy dispersive X ray analysis; Fluorescence; Food industry; Industry; Laser beam welding; Laser induced breakdown spectroscopy; Lasers; LIBS; Measurement; Measurement methods; Mechanical properties; Microstructure; Phase ratio; Production methods; Shipping; Spectroscopy; Stainless steel; Thin films; TIG welding; Weight reduction; X ray analysis; X ray fluorescence analysis; X rays; X-ray fluorescence; X-ray spectroscopy; XRF; Duplex stainless steels; TIG welding; EDS; LIBS; XRF; Element vaporization
• ISSN: 0584-8547; 1873-3565
• DOI: 10.1016/j.sab.2022.106439

Duplex steels (DSS) are used in all industries where corrosion problems play a major role. Examples include the chemical industry, the food industry and shipping industries. DSS have a balanced phase ratio of ferrite (α) and austenite (γ). Unlike single-phase stainless steels, DSS combine the advantages of these and can therefore fit many industry requirements, such as weight saving or high mechanical strength. When these steels are welded, alloying elements can burn off and condense as thin layers on cold surface regions. This loss of chemical elements can lead to changes in the microstructure. With the help of Laser-Induced Breakdown Spectroscopy (LIBS), chemical element distributions were visualized. The results were compared with those of conventional measurement methods, such as energy dispersive X-ray analysis (EDS) and X-ray fluorescence analysis (XRF), and the results from LIBS could be validated. LIBS is suitable as a fast, straightforward measurement method for producing line scans along the weld seam and provides spatially resolved information on accumulation phenomena of burned off alloying elements. LIBS is very well suited for the detection of sub-surface elements due to the exclusively superficial ablation of the material. In addition, the measurement method has been calibrated so that quantitative statements about element concentrations can also be made. [Display omitted] •The chemical concentration curves of both LIBS and EDX line scans across the weld seam of DSS are in fair agreement.•LIBS and XRF mappings show comparable concentration distributions of the main alloying elements in DSS.•Thin surface layers on the HAZ from burned-off alloying elements could be visualized with LIBS, XRF and EDS mappings.•LIBS results were validated with conventional measurement methods XRF, EDS, thus LIBS is suitable for weld seam monitoring.