Research on directional solidification combined with electron beam melting and refining for recycling of FGH4096 alloy scraps

• Published in: Separation and purification technology Vol. 351; p. 127874
• Main Authors: Chang, Kai, Tan, Yi, Bai, Rusheng, Dong, Gengyi, Li, Pengting, Liu, Yufeng, Yuan, Hua, Wang, Yinong
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 24.12.2024
• Subjects: Collision-agglomeration; Electron beam melting and refining; FGH4096; Inclusion; Purification; Collision-agglomeration; Inclusion; Purification; Electron beam melting and refining; FGH4096
• ISSN: 1383-5866
• DOI: 10.1016/j.seppur.2024.127874

•EBMR is firstly proposed to prepare powder superalloy ingots with high-purity.•The secondary dendrite spacing and the size of γ′ phases are significantly reduced.•O, N, and number density of inclusions are reduced to 5.7, 0.6 ppmw and 5.11 mm−2.•The mechanism of droplet transfer mode has been proposed to predict the melting temperature.•Marangoni effect and extremely high melt surface temperature significantly increase the chances of inclusion collision. The constraints of traditional manufacturing techniques have led to the generation of a considerable amount of waste superalloy, causing substantial resource wastage. The primary concern with waste superalloys lies in the excessive presence of inclusions and impurity elements, rendering them unsuitable for further utilization. This study proposes the use of directional solidification combined with electron beam melting and refining (EBMR) to prepare FGH4096 superalloy ingots (Φ120 mm), which offers a promising approach to produce large-sized powder superalloy master alloy ingots with high-purity and high homogeneity. It is found that the secondary dendrite arm spacing and the size of the γ’ phase in the alloy are significantly reduced after EBMR treatment. The concentration of O and N can be decreased to 5.7 and 0.6 ppmw, respectively. The size of inclusion can be reduced below 8.69 μm and the inclusion numbers reduce by over 50 % compared with both conventional ingots. A droplet transfer mode and melt convection mode mechanism have been proposed, which accurately predicts the melting temperature and melt flow. A quantitative study is conducted on the influence of inclusion density, the contact angle between inclusions and melt, and the surface tension of the melt on capillary forces. The results indicate that the capillary forces between inclusions in the melt range from 1.8 × 10−19 N and 1.9 × 10−17 N. Furthermore, the collision-aggregation behavior of inclusions in the melt is discussed, and an estimate of the tendency of inclusion collision-aggregation is provided. The enrichment of inclusions in the EBMR ingot is primarily the result of turbulent collision. The Marangoni effect and the extremely high surface temperature of the melt promote the collision and agglomeration of inclusions, causing them to accumulate rapidly at the melt surface. Moreover, the thorough removal of inclusions through the decomposition and dissolution process of the electron beam offers theoretical backing for the preparation of superalloys through electron beam melting and high-purity refining.