Developments in Binuclear Late Transition Metal Catalysts for Ethylene Homo- and Copolymerization

Recent advances in the research of late transition metal (Ni) salicylaldimine bimetallic catalysts in ethylene polymerization and copolymerization of ethylene with comonomers have been introduced. The effect of positioning two polymerization-active metal centers in close proximity on catalytic activ...

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Bibliographic Details
Published inE3S web of conferences Vol. 406; p. 2022
Main Authors Cao, Wenyao, Ren, Chuanli, Liu, Shaofeng
Format Journal Article Conference Proceeding
LanguageEnglish
Published Les Ulis EDP Sciences 01.01.2023
Subjects
Bimetals
Catalysts
Catalytic activity
Copolymerization
Ethylene
Molecular weight
Molecular weight distribution
Polymerization
Synergistic effect
Transition metals
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Summary:Recent advances in the research of late transition metal (Ni) salicylaldimine bimetallic catalysts in ethylene polymerization and copolymerization of ethylene with comonomers have been introduced. The effect of positioning two polymerization-active metal centers in close proximity on catalytic activity, molecular weight, molecular weight distribution, and levels of branching are thoroughly documented. The synergistic effect of these binuclear catalysts compared to their mononuclear analogs is the subject of this review.
Bibliography:ObjectType-Conference Proceeding-1
SourceType-Conference Papers & Proceedings-1
content type line 21
ISSN:2267-1242
2555-0403
2267-1242
DOI:10.1051/e3sconf/202340602022