Synthesis and complexation of the novel tridentate anionic organogallate ligands, [Me2Ga(N2C5H7)(OCH2CH2SR)]− (R = Et or Ph)
The synthesis and complexation of the novel tridentate chelating anionic organogallate ligands [Me 2 Ga(N 2 C 5 H 7 )(OCH 2 CH 2 SR)] − (R = Et or Ph) have been investigated. A variety of octahedral molybdenum, tungsten, and manganese carbonyl compounds have been studied in which the organogallate l...
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| Published in | Canadian journal of chemistry Vol. 59; no. 9; pp. 1331 - 1341 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Ottawa, Canada
NRC Research Press
01.05.1981
|
| Online Access | Get full text |
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| Summary: | The synthesis and complexation of the novel tridentate chelating anionic organogallate ligands [Me
2
Ga(N
2
C
5
H
7
)(OCH
2
CH
2
SR)]
−
(R = Et or Ph) have been investigated. A variety of octahedral molybdenum, tungsten, and manganese carbonyl compounds have been studied in which the organogallate ligand (R = Et) is in the fac coordination mode. In addition tetrahedral "Cu*PPh
3
" and "Ni(NO)" complexes have been characterized which display fluxional behaviour in solution. The dearth of derivatives available using the ligand where R = Ph is attributed to steric factors. |
|---|---|
| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v81-196 |