THE STRUCTURES AND CHEMISTRY OF THE PRODUCTS FROM THE REACTION OF AMINO ALCOHOLS WITH CARBON DISULPHIDE

A study of the infrared spectra of the oxazoline derivatives, which are formed by the condensation of carbon disulphide with amino alcohols, shows that they possess the oxazolidine-2-thione structure rather than the tautomeric 2-thiol-2-oxazoline structure. 2-Benzylamino-4,4-dimethyl-2-oxazoline was...

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Bibliographic Details
Published inCanadian journal of chemistry Vol. 34; no. 6; pp. 815 - 820
Main Authors Skulski, M, Garmaise, D. L, McKay, A. F
Format Journal Article
LanguageEnglish
Published Ottawa, Canada NRC Research Press 01.06.1956
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Summary:A study of the infrared spectra of the oxazoline derivatives, which are formed by the condensation of carbon disulphide with amino alcohols, shows that they possess the oxazolidine-2-thione structure rather than the tautomeric 2-thiol-2-oxazoline structure. 2-Benzylamino-4,4-dimethyl-2-oxazoline was formed by the reaction of benzylamine with 2-methylmercapto-4,4-dimethyl-2-oxazolinium iodide. 5-Diethylaminomethyl-2-oxazolidone and its methylation product also have been prepared.
ISSN:0008-4042
1480-3291
DOI:10.1139/v56-105