A facile synthesis of Mn3O4/Fe3O4 superparamagnetic nanocomposites by chemical precipitation: Characterization and application in dye degradation

• Published in: Materials research bulletin Vol. 49; pp. 544 - 551
• Main Authors: Silva, Gabriela C., Ciminelli, Virginia S.T., Ferreira, Angela M., Pissolati, Nathalia C., Paiva, Paulo Renato P., López, Jorge L.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.01.2014
• Subjects: A. Composites; A. Nanostructures; B. Chemical synthesis; D. Catalytic properties; D. Magnetic properties; B. Chemical synthesis; A. Composites; A. Nanostructures; D. Catalytic properties; D. Magnetic properties
• ISSN: 0025-5408; 1873-4227
• DOI: 10.1016/j.materresbull.2013.09.039

•Facile synthesis of a Mn3O4/Fe3O4 superparamagnetic nanocomposite.•The nanocomposite removes 93% of a dye from water in approximately 1h.•The nanocomposite is easily separated from solution by magnetic field. Degradation of methylene blue (MB) is investigated using Mn3O4 as an oxidant. Discrete Mn3O4 particles and Mn3O4/Fe3O4 nanocomposites are synthesized via coprecipitation by using air as an oxidant in the absence and presence of previously synthesized magnetite nanoparticles, respectively. Characterization results show that superparamagnetic magnetite nanoparticles of ∼10nm were synthesized. The Mn3O4 synthesis in the presence of these magnetite nanoparticles favors the formation of a pure, highly ordered Mn3O4/Fe3O4 superparamagnetic nanocomposite, which can be separated by an external magnetic field. This nanocomposite is applied to the oxidative decolorization of methylene blue (MB) and is capable of catalyzing the complete N-demethylation of MB, forming thionine as the final product and removing 93% of the dye in approximately 1h.