A relatively large NMR shielding anisotropy: Hydrogen in zirconium chloride monohydride

The shielding tensor of 1H in ZrClH 1.0 was determined in the rigid-lattice temperature region utilizing multiple-pulse NMR to remove static dipolar interactions. The tensor was found to be axially symmetric, with an anisotropy of 102.5 ± 3 ppm. Implications of this value in the two-dimensional meta...

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Bibliographic Details
Published inJournal of magnetic resonance (1969) Vol. 34; no. 2; pp. 333 - 337
Main Authors Murphy, P.Dubois, Gerstein, B.C
Format Journal Article
LanguageEnglish
Published Elsevier Inc 01.01.1979
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Summary:The shielding tensor of 1H in ZrClH 1.0 was determined in the rigid-lattice temperature region utilizing multiple-pulse NMR to remove static dipolar interactions. The tensor was found to be axially symmetric, with an anisotropy of 102.5 ± 3 ppm. Implications of this value in the two-dimensional metal structure of ZrClH 1.0 are discussed.
ISSN:0022-2364
1557-8968
DOI:10.1016/0022-2364(79)90009-X