Palladium-catalyzed Reaction of Olefins and Acetylenes with Iodoferrocenes

Iodoferrocene (1) reacts readily with olefinic compounds in the presence of a catalytic amount of palladium(II) acetate to produce alkenylferrocene derivatives. In the presence of a copper(I) iodide and palladium complex, 1 also reacts with acetylene to afford diferrocenylacetylene.

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Bibliographic Details
Published inBulletin of the Chemical Society of Japan Vol. 50; no. 4; pp. 1021 - 1022
Main Authors Kasahara, Akira, Izumi, Taeko, Maemura, Mitsugi
Format Journal Article
LanguageEnglish
Published The Chemical Society of Japan 01.04.1977
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Summary:Iodoferrocene (1) reacts readily with olefinic compounds in the presence of a catalytic amount of palladium(II) acetate to produce alkenylferrocene derivatives. In the presence of a copper(I) iodide and palladium complex, 1 also reacts with acetylene to afford diferrocenylacetylene.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.50.1021