Enhancement of Cs vaporization from simulated granular ash through thermal treatment in N2 atmosphere with the addition of a mixture of CaCl2 and CaO

• Published in: Fuel (Guildford) Vol. 214; pp. 409 - 415
• Main Authors: Jiao, Facun, Kinoshita, Norikazu, Kawaguchi, Masato, Asada, Motoyuki, Honda, Maki, Sueki, Keisuke, Ninomiya, Yoshihiko
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.02.2018
• Subjects: Cesium removal; Granular ash; Incineration; Mixture of CaCl2 and CaO; Mixture of CaCl2 and CaO; Cesium removal; Granular ash; Incineration
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2017.11.018

•Vaporization of Cs in simulated granular ash was examined.•CaCl2 and CaO were used as additives.•Addition of CaCl2 and CaO together enhanced Cs vaporization.•Cl-aluminosilicates were formed when CaCl2 and CaO coexisted in ash. This study aims to clarify the vaporization propensity of Cs in simulated granular ash through thermal treatment in N2 atmosphere at 1100–1500 °C with the addition of a mixture of CaCl2 and CaO. XRD and XPS were employed to specify Cl-bearing species in the treated ash. The results indicated that CaCl2 addition facilitated the vaporization of Cs. The vaporization ratio of Cs as a function of temperature was nonlinear. The ash melt formed at 1400 °C constrained the diffusion of Cs species by blocking the pores and/or decreasing the surface area of the ash particles which, however, was compensated by increasing the temperature to 1500 °C. The addition of the mixture of CaCl2 and CaO highly promoted the vaporization of Cs in the ash compared to that of the addition of CaCl2. Formation of wadalite/igumnovite through chemical reactions among granular ash, CaCl2 and CaO, as well as more liquid produced by additional CaO, were in favor of the reaction of Cs with Cl, thereby synergistically promoting the Cs vaporization. Addition of the mixture of CaCl2 and CaO is highly recommended to remove Cs from Cs-contaminated incineration ash during thermal treatment.