2-Chloroethylamine·trifluoromethanesulfonate combined with 18-crown-6: a ferroelectric with excellent dielectric switching properties

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 52; no. 32; pp. 11196 - 1122
• Main Authors: Song, Ning, Ying, Ting-Ting, Tan, Yu-Hui, Tang, Yun-Zhi, Liao, Juan, Wang, Li-Juan, Wang, Fang-Xin, Wan, Ming-Yang
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 15.08.2023
• Subjects: Crown ethers; Ferroelectric materials; Ferroelectricity; Ferroelectrics; Functional materials; Harmonic response; Hysteresis loops; Phase transitions; Positive ions; Symmetry; Transition temperature
• ISSN: 1477-9226; 1477-9234; 1477-9234
• DOI: 10.1039/d3dt01426f

Ferroelectric materials are not only important electronic functional materials, but also considered as the most promising intelligent basic materials, because they show good application prospects. Therefore, it is an urgent task to develop and explore new ferroelectric material systems. In addition, the most important feature of crown ethers is their ability to complex with positive ions, which is extremely useful in synthesis. We report that [NH 3 C 2 H 4 Cl(18-crown-6)](CF 3 SO 3 ) ( 1 ) has a phase transition temperature T c = 255 K, and there is an obvious SHG switch below T c . At the same time, the saturation polarization value P s = 1.25 μC cm −2 is obtained from the hysteresis loop, which directly proves the ferroelectric nature of compound 1 . It is noteworthy that the second harmonic response test of compound 1 shows a symmetric transition from a non-centrosymmetric to a centrosymmetric point group, that is a symmetry break from the paraelectric phase to the ferroelectric phase. This work is expected to promote the further exploration of organic crown ether ferroelectrics and provide a way to design and synthesize organic crown ether ferroelectrics. A new type of 18-crown ether-6-based molecular ferroelectric [NH 3 C 2 H 4 Cl(18-crown-6)](CF 3 SO 3 ) ( 1 ) undergoes a ferroelectric phase transition at 255 K and exhibits a flexible switchable SHG effect. 1 has a polarization value P s of 1.25 μC cm −2 .