A simultaneous depolymerization and hydrodeoxygenation process to produce lignin-based jet fuel in continuous flow reactor

• Published in: Fuel processing technology Vol. 263; p. 108129
• Main Authors: Kumar, Adarsh, Bell, David C., Yang, Zhibin, Heyne, Joshua, Santosa, Daniel M., Wang, Huamin, Zuo, Peng, Wang, Chongmin, Mittal, Ashutosh, Klein, Darryl P., Manto, Michael J., Chen, Xiaowen, Yang, Bin
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.2024; Elsevier
• Subjects: Continuous flow reactor; Engineered catalyst; Lignin-based jet fuel; Simultaneous depolymerization and hydrodeoxygenation; Tier α fuel property; Continuous flow reactor; Engineered catalyst; Simultaneous depolymerization and hydrodeoxygenation; Tier α fuel property; Lignin-based jet fuel
• ISSN: 0378-3820
• DOI: 10.1016/j.fuproc.2024.108129

Economical production of lignin-based jet fuel (LJF) can improve the sustainability of sustainable aviation fuels (SAFs) as well as can reduce the overall greenhouse gas emissions. However, the challenge lies in converting technical lignin polymer from biorefinery directly to jet fuel in a continuous operation. In this work, we demonstrate a simultaneous depolymerization and hydrodeoxygenation (SDHDO) process to produce lignin-based jet fuel from the alkali corn stover lignin (ACSL) using engineered Ru-HY-60-MI catalyst in a continuous flow reactor, for the first time. The maximum carbon yield of LJF of 17.9 wt% was obtained, and it comprised of 60.2 wt% monocycloalkanes, and 21.6 wt% polycycloalkanes. Catalyst characterization of Ru-HY-60-MI suggested there was no significant change in HY zeolite structure and its crystallinity after catalyst engineering. Catalyst characterizations performed post the SDHDO experiments indicate presence of carbon and K content in the catalyst. K content presence in the spent catalyst was due to K+ ion was exchanged between lignin solution and HY-60 while carbon presence validated the SDHDO chemistry on the catalyst surface. Tier α fuel property testing indicates that LJF production using SDHDO chemistry can produce SAF with high compatibility, good sealing properties, low emissions, and high energy density for aircraft. [Display omitted] •Simultaneous depolymerization and HDO of lignin demonstrated in continuous flow reactor.•Aviation fuel range cycloalkanes produced with 17.9 wt% carbon yield.•Tier alpha fuel properties identified these cycloalkanes as a good fit for aviation fuel.•Exchange of K+ ion from lignin solution and coke deposition to catalyst surface observed.