Temperature dependent dielectric relaxation spectroscopy of amyl acetate-xylene solutions – An approach to molecular and co-operative dynamics

• Published in: Journal of the Indian Chemical Society Vol. 100; no. 10; p. 101088
• Main Authors: Birajdar, S.S., Deshmukh, A.R., Kumbharkhane, A.C., Suryawanshi, D.B.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.10.2023
• Subjects: Co-operative domains (CDs); CPS; Kirkwood correlation factor; Luzar model; Relaxation time; Static dielectric permittivity; Thermodynamic parameters and TDR; Kirkwood correlation factor; Luzar model; CPS; Static dielectric permittivity; Co-operative domains (CDs); Thermodynamic parameters and TDR; Relaxation time
• ISSN: 0019-4522
• DOI: 10.1016/j.jics.2023.101088

Dielectric relaxation parameters of AMA-Xylene solutions have been investigated thoroughly to discern the associativeness as well as heterogeneous behavior among the hetero molecules in the solutions such that dielectric constant (εo) and relaxation time (τ) of solutions has been determined. Complex permittivity spectra (CPS) for Amyl Acetate (AMA)-Xylene solutions were measured in 10 MHz–50 GHz frequency range using Time domain reflectometry (TDR) technique. It is exciting to explore the cooperative nature and association between AMA-Xylene. With co-operative domains (CDs), dynamics in AMA-AMA and AMA-Xylene molecules have been explicated while Kirkwood validates CDs with diverse exchanges through bonding. The experimental values of εo are compared with theoretical values obtained from the molecular parameters suggested by the Luzar. Thermodynamic parameters for AMA-Xylene show positive values of Enthalpy and Entropy for all concentrations, indicating that the system is endothermic and less ordered. Gibbs free energy decreases with increase in volume fraction of amyl acetate (VAMA). [Display omitted] •Complex permittivity of AMA-Xylene solutions shows Debye type relaxation process.•Increasing VAMA causes rise in εo with τ such that presence of CDAMA, CDAMA-XYL and CDXYL is confirmed.•geff explains impact of CDs through hydrogen bonding with diverse interactions between AMA and Xylene molecules.•Luzar model provides a good theoretical basis for computation of molecular parameters.•Positive results of Enthalpy and Entropy at all concentrations indicate endothermic and less ordered system.