Microwave assisted synthesis of an unusual dinitro phytochemical

A novel dinitro secondary metabolite, 2-nitro-4-(2'-nitroethenyl)phenol from a marine source, has been prepared via highly accelerated, microwave assisted, nitration reactions using mild reagents. ipso-substitution of a carboxy group by a nitro group is discussed. (C) 2003 Elsevier Ltd. All rig...

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Bibliographic Details
Published inTetrahedron letters Vol. 45; no. 6; pp. 1179 - 1181
Main Authors Bose, AK, Ganguly, SN, Manhas, MS, Srirajan, Bhattacharjee, A, Rumthao, S, Sharma, AH
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 02.02.2004
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ipso-substitution
antifungal compounds
dinitrostyrene
phytochemicals
clay-based reactions
mild nitration
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Summary:A novel dinitro secondary metabolite, 2-nitro-4-(2'-nitroethenyl)phenol from a marine source, has been prepared via highly accelerated, microwave assisted, nitration reactions using mild reagents. ipso-substitution of a carboxy group by a nitro group is discussed. (C) 2003 Elsevier Ltd. All rights reserved.
ISSN:0040-4039
DOI:10.1016/j.tetlet.2003.12.002