Photocatalytically active ZnO flaky nanoflowers for environmental remediation under solar light irradiation: effect of morphology on photocatalytic activity

• Published in: Bulletin of materials science Vol. 44; no. 4; p. 247
• Main Authors: Suganya Josephine, G A, Jayaprakash, K, Meenakshi, G, Sivasamy, A, Nirmala Devi, G, Viswanath, R N
• Format: Journal Article
• Language: English
• Published: Bangalore Indian Academy of Sciences 01.12.2021; Springer Nature B.V
• Subjects: Ammonia; Catalytic activity; Caustic soda; Chemistry and Materials Science; Dyes; Effluents; Engineering; Ethanol; Fourier transforms; Light; Light irradiation; Materials Science; Membrane separation; Metal oxides; Microscopy; Morphology; Nanomaterials; Nanorods; Nanospheres; Nitrates; Particle size; Photocatalysis; Pollutants; Sodium; Spectrum analysis; Surfactants; Zinc oxide; Zinc oxides; India; Environmental remediation; nanoflowers; photocatalysis; nanostructures; zinc oxide
• ISSN: 0250-4707; 0973-7669
• DOI: 10.1007/s12034-021-02531-1

ZnO-flaky-like nanoflowers with enhanced photocatalytic activity were synthesized by a new hydrothermal technique. The material was characterized and the photocatalytic studies were conducted under solar light irradiation for a model azo dye, Orange G. The material was compared with ZnO nanosphere and nanorod. The results showed the particle size of the nanostructures as a nanorod is 62–81 nm, as a nanosphere is 40–70 nm and as flaky nanoflowers is 20–30 nm (thickness of the flake). The photocatalytic activity showed an enhanced 2-fold increase in the activity for nanoflowers when compared to nanorods and spheres. The Brauner–Emmett–Teller results showed that the nanoflowers (14.197 m 2  g −1 ) had a higher surface area nearly 3.5 times when compared to the nanospheres (4.06 m 2  g −1 ) and seven times with nanorods (2.1 m 2  g −1 ) which is the possibility of such high photocatalytic activity. The smaller particle size and the arrangement of nanoflowers play an important role in enhanced photocatalytic activity. Graphic abstract ZnO flaky-nanoflowers as enhanced photocatalyst for the degradation of organics under solar light irradiation. It showed a two-fold increase in activity than ZnO nanospheres and nanorods.