The first ionic liquids promoted conjugate addition of azide ion to α,β-unsaturated carbonyl compounds

The first, highly efficient conjugate addition of azide ion to alpha,beta-unsaturated carbonyl compounds promoted by the simple recyclable ionic liquids, bmimPF(6) and bmimBF(4), are described. (C) 2003 Elsevier Ltd. All rights reserved.

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Bibliographic Details
Published inTetrahedron letters Vol. 45; no. 6; pp. 1219 - 1221
Main Authors Xu, Li-Wen, Li, Lyi, Xia, Chun-Gu, Zhou, Shao-Lin, Li, Jing-Wei
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier 02.02.2004
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ionic liquid
HYDROGEN AZIDE
IMINES
COMPLEXES
ENONES
conjugate addition
EFFICIENT
azide
EPOXIDATION
enone
AMINO-ACID-DERIVATIVES
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Summary:The first, highly efficient conjugate addition of azide ion to alpha,beta-unsaturated carbonyl compounds promoted by the simple recyclable ionic liquids, bmimPF(6) and bmimBF(4), are described. (C) 2003 Elsevier Ltd. All rights reserved.
ISSN:0040-4039
DOI:10.1016/j.tetlet.2003.11.129